Biphemp
WebMar 13, 1991 · The MeO-BIPHEP diphosphine 5a proved to be as efficient as the previously described BIPHEMP diphosphine ((6,6′-dimethylbiphenyl-2,2′-diyl)bis(diphenylphosphine)) in enantioselective isomerizations and hydrogenations. Citing Literature. Volume 74, Issue 2. 13 March 1991. Pages 370-389. Related; WebThe novel species [RuCl(PPh){()-biphemp}] and [RuH(η-BH)(PPh){()-biphemp}][biphemp = 2,2′-dimethyl-6,6′-bis(diphenylphosphino)biphenyl] have been synthesized; has a labile …
Biphemp
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WebMar 16, 2024 · For example, the 1,6-enyne proceeds reaction with triethylsilane in the presence of cationic Rh and ( R )-biphemp to give hydrosilylated alkylidene cyclopentane in 92% ee (Scheme \(\PageIndex{17}\)). Subsequently, chiral Rh complex containing spiro diphosphine ( R )-sdp is found to be effective for this process. Webpossessing atropisomeric ligands (e.g. Binap and Biphemp ) served as catalysts precursors for a highly selective hydrogenation giving enantioselectivity of up to 90 % e.e. (entries 8 and 14). Using C2-symmetric bis (phospholanes) such as the (R,R)-Me-Duphos 17 Ru(T~~-(CH~)~CHCH~)~ complex led to 4 and the
WebFeb 2, 2024 · ligands such as MeO–BIPHEP or BIPHEMP etc. 4. Dynamic kinetic resolution Racemic substrates possessing an epimerisable center such as a-substituted b-ketoesters can be converted to one single a-substituted b-hydroxyester under con-trolled hydrogenation conditions. This reaction where the chiral ruthenium(II) catalyst can select one of the WebFeb 12, 2024 · Chiral sulfoxide-oxazoline ligands were the earliest nitrogen-containing chiral sulfoxide ligands used in asymmetric synthesis. This kind of ligand can be prepared by ortho-lithiation of the parent 2-phenyloxazoline with n-BuLi and addition of either (S)- or (R)-arylmenthylsulfinate [15,16,17].In 1994, Williams and co-workers firstly used the chiral …
WebCatalog Number. Description. CAS Number. 96-3655. Solvias (R)-MeO-BIPHEP Ligand Kit. 96-3656. Solvias (S)-MeO-BIPHEP Ligand Kit. Phosphorus › Compounds. View Structures.
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